I've never baked with it, but I do know that sometimes the canned stuff is pretty nasty tasting or smelling. I'd open the can, taste and smell it. If it passes that test, I'd use it.
The morning breeze has secrets to tell you. Do not go back to sleep. Rumi
I made oatmeal muffins and they were sooooo good. They came home, ate them, boasted about them, and that's when I told them I used goat's milk. My husband loved them too. I guess I'll be keeping extra cans around for baking (until we get our goats for our own milk this year).